Issue 21, 1986

Stereoselective oxygenation of 2,3-diaryloxiranes by irradiation of electron donor–acceptor complexes of tetracyanoethylene

Abstract

On irradiation of the electron donor–acceptor complexes of 2,3-diaryloxiranes with tetracyanoethylene (TCNE) in the presence of oxygen, cis-trioxolanes are formed stereoselectively; a nonstereoselective [3 + 2]cycloaddition with TCNE competes with trioxolane formation.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1577-1579

Stereoselective oxygenation of 2,3-diaryloxiranes by irradiation of electron donor–acceptor complexes of tetracyanoethylene

T. Miyashi, M. Kamata and T. Mukai, J. Chem. Soc., Chem. Commun., 1986, 1577 DOI: 10.1039/C39860001577

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