The prochiral (3b), derived from glycerol, was transformed by enantioselective, enzymatic hydrolysis into the central chiral building block (R)-(4) of high enantiomeric purity, which was further elaborated into a variety of chiral building blocks with the glycerol skeleton.
D. Breitgoff, K. Laumen and M. P. Schneider, J. Chem. Soc., Chem. Commun., 1986, 1523 DOI: 10.1039/C39860001523
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