Issue 20, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

A new Rh6 geometry in the first Rh6 phosphido-bridged cluster: synthesis and structure of Rh6(µ-But2P)4(CO)6(µ-CO)2(µ-H)2

Atta M. Arif,   Duane E. Heaton  and  Richard A. Jones  

Abstract

Reaction of Rh4(CO)12 with But2PH (Rh : P = 3:2) in toluene under reflux yields the Rh6 phosphido-bridged cluster Rh6(µ-But2P)4(CO)6(µ-CO)2(µ-H)2(60%) which has an unusual Rh6 core geometry consisting of a Rh4 tetrahedron bridged on opposite edges by two more Rh atoms.

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Article information

DOI
https://doi.org/10.1039/C39860001506
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1506-1507

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A new Rh6 geometry in the first Rh6 phosphido-bridged cluster: synthesis and structure of Rh6(µ-But2P)4(CO)6(µ-CO)2(µ-H)2

A. M. Arif, D. E. Heaton and R. A. Jones, J. Chem. Soc., Chem. Commun., 1986, 1506 DOI: 10.1039/C39860001506

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