5,5,10,10-Tetrachlorotricyclo[7.1.0.04,6]deca-2,7-diene (1) was labelled at the chlorine carrying carbon atoms; its pyrolysis yielded dichlorozulenes (2), (3), and (4) in which no separation of labelled carbon atoms and substituent chlorine had occurred: mechanisms for the rearrangements are proposed.
E. V. Dehmlow, D. Balschukat, P. P. Schmidt and R. Krause, J. Chem. Soc., Chem. Commun., 1986, 1435 DOI: 10.1039/C39860001435
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