Issue 18, 1986

Synthesis of carbocyclic analogues of D-glucosamine and L-idosamine from D-flucosamine

Abstract

Derivatives of pseudo-D-glucosamine and pseudo-L-idosamine have been prepared from the chiral cyclohexanone (1) by a short sequence, including methoxy-methylenation or methylenation, followed by stereoselective oxymercuration or hydroboration, respectively of the resulting vinyl ether (2) and exocyclic methylene (3).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1399-1401

Synthesis of carbocyclic analogues of D-glucosamine and L-idosamine from D-flucosamine

D. H. R. Barton, S. D. Géro, S. Augy and B. Quiclet-Sire, J. Chem. Soc., Chem. Commun., 1986, 1399 DOI: 10.1039/C39860001399

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