t-Butyl hydroperoxide and an alkyl-lithium in dry tetrahydrofuran are shown to epoxidise α,β-unsaturated esters and sulphones efficiently in a stereo- and regio-specific manner, while esters of chiral alcohols undergo diastereofacially selective epoxidation.
C. Clark, P. Hermans, O. Meth-Cohn, C. Moore, H. C. Taljaard and G. van Vuuren, J. Chem. Soc., Chem. Commun., 1986, 1378 DOI: 10.1039/C39860001378
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