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The interconversion of isobutyrate and n-butyrate in Streptomyces cinnamonensis, which occurs by an intramolecular carbon skeleton rearrangement, is shown by isotopic labelling experiments also to involve the 1,2-shift of a hydrogen from the pro-(S) methyl of isobutyryl-CoA to the 3-pro-(S) position in n-butyryl-CoA.
K. Reynolds, D. Gani and J. A. Robinson, J. Chem. Soc., Chem. Commun., 1986, 1334 DOI: 10.1039/C39860001334
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