A new class of 14-membered tetra-azamacrocycle (cyclam) functionalised with a pendent pyridine ligand is reported; the X-ray crystal structure of its NiII complex (7a) provides the first unequivocal example of co-ordination of the pyridyl side-arm to the centrally placed metal ion.
E. Kimura, T. Koike, H. Nada and Y. Iitaka, J. Chem. Soc., Chem. Commun., 1986, 1322 DOI: 10.1039/C39860001322
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