Zirconium(III) complexes containing the chelated [graphic omitted]Ph2 moiety hydrogenate unsaturated hydrocarbons in a rapid catalytic process with specific selectivity, giving a quantitative yield of cyclo-octene from 1,3- and 1,5-cyclo-octadiene and of 1,2,3,4-tetraphenylbutane from diphenylacetylene.
R. Choukroun, M. Basso-Bert and D. Gervais, J. Chem. Soc., Chem. Commun., 1986, 1317 DOI: 10.1039/C39860001317
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