The S= 9/2 ground state of a linear MnIICuIIMnII trinuclear complex arises from the parallel alignment of the local spins (5/2) of the two terminal MnII ions through antiferromagnetic interactions with the local spin (1/2) of the central CuII ion.
Y. Pei, Y. Journaux, O. Kahn, A. Dei and D. Gatteschi, J. Chem. Soc., Chem. Commun., 1986, 1300 DOI: 10.1039/C39860001300
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