A convenient route to trans-2,6-dialkylpiperidines by cycloaddition of alkenes to 2-alkyl-2,3,4,5-tetrahydropyridine oxides followed by reductive cleavage of the resulting isoxazolidine is illustrated by a synthesis of the fire ant-venom alkaloid, solenopsin.
W. Carruthers and M. J. Williams, J. Chem. Soc., Chem. Commun., 1986, 1287 DOI: 10.1039/C39860001287
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