The synthesis of the C-9 to C-18 fragment of macbecins I and II has been accomplished via a novel cyclisation and stereospecific cuprate opening of a chiral epoxide.
R. Baker, W. J. Cummings, J. F. Hayes and A. Kumar, J. Chem. Soc., Chem. Commun., 1986, 1237 DOI: 10.1039/C39860001237
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