Issue 15, 1986

The acid promoted disproportionation of a vanadium(IV) phenolate: implications for vanadium uptake in tunicates

Abstract

Under anaerobic conditions VIVO(salen)(salen =N,N′-ethylenebis-salicylideneaminato) undergoes an acid promoted disproportionation to yield a VIII(salen) species and VVO(salen)+ which upon addition of chloride ion react via back electron transfer to yield VIVO(salen) and VIVCl2(salen).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1218-1219

The acid promoted disproportionation of a vanadium(IV) phenolate: implications for vanadium uptake in tunicates

J. A. Bonadies, V. L. Pecoraro and C. J. Carrano, J. Chem. Soc., Chem. Commun., 1986, 1218 DOI: 10.1039/C39860001218

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