The [4 + 2] and [2 + 2] intramolecular cycloadditions to allenecarboxylates are strongly affected by conformational differences of the substrates in the transition state.
M. Yoshida, M. Hiromatsu and K. Kanematsu, J. Chem. Soc., Chem. Commun., 1986, 1168 DOI: 10.1039/C39860001168
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