The fate of the hydrogen atoms originating from [2-13C,2-2H3]acetate was investigated in the biosynthesis of sitosterol (5) in cultured cells of Rabdosia japonica Hara and ergosterol (6) in yeast and the 1,2-hydride shifts, 20-H from C-17 and 17-H from C-13, were verified.
S. Seo, U. Sankawa, H. Seto, A. Uomori, Y. Yoshimura, Y. Ebizuka, H. Noguchi and K. Takeda, J. Chem. Soc., Chem. Commun., 1986, 1139 DOI: 10.1039/C39860001139
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