A chiral ferrocenylphosphine–palladium catalyst effects a highly selective kinetic resolution (kS/kR= 14) of racemic allyl acetates such as 1-[(E)-styryl]-2-methylpropyl acetate in asymmetric allylic alkylation.
T. Hayashi, A. Yamamoto and Y. Ito, J. Chem. Soc., Chem. Commun., 1986, 1090 DOI: 10.1039/C39860001090
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