The crystal structure of a 1-aminodiazaphosphene derivative shows that it possesses an unusually long PN bond; it shows high reactivity towards CO2 and CS2.
U. Dressler, E. Niecke, S. Pohl, W. Saak, W. W. Schoeller and H.-G. Schäfer, J. Chem. Soc., Chem. Commun., 1986, 1086 DOI: 10.1039/C39860001086
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