Issue 14, 1986

Pre-isoflavonoid stages in the biosynthesis of amorphigenin: ring-D formation and ring-A migration

Abstract

Despite low incorporations of doubly labelled [13C]acetate during the biosynthesis of amorphigenin by Amorpha fruticosa seedlings, it has been possible to solve the ring-D folding by an INADEQUATE n.m.r. experiment; new proposals are made for the mechanism of the enzyme catalysed flavanone–isoflavone transformation step.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1063-1065

Pre-isoflavonoid stages in the biosynthesis of amorphigenin: ring-D formation and ring-A migration

L. Crombie, I. Holden, N. Van Bruggen and D. A. Whiting, J. Chem. Soc., Chem. Commun., 1986, 1063 DOI: 10.1039/C39860001063

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