The ethyl protons of the complex [Co(η-C5Me5)(C2H5)(PMe2Ph)]+ which contains a 3-centre, 2-electron M–H–C interaction, interchange by a combination of three identifiable processes which have been modelled by Extended Hückel Molecular Orbital (EHMO) calculations: M–H cleavage/methyl rotation, inversion of chirality at cobalt, and β-elimination/olefin rotation.
R. B. Cracknell, A. G. Orpen and J. L. Spencer, J. Chem. Soc., Chem. Commun., 1986, 1005 DOI: 10.1039/C39860001005
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