Issue 12, 1986

Stereochemistry of acidolysis of cyclohept-2-enyl-silanes and -stannanes

Abstract

Direct 2H n.m.r. analysis of the 2H-substituted 3- and 4-methylcycloheptenes produced by acid cleavage (CF3CO2D) of mixtures of 4- and 7-methylcyclohept-2-enyltrimethyl-silanes and -stannanes confirms stereospecific γ-anti attack by the electrophile.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 954-955

Stereochemistry of acidolysis of cyclohept-2-enyl-silanes and -stannanes

W. Kitching, B. Laycock, I. Maynard and K. Penman, J. Chem. Soc., Chem. Commun., 1986, 954 DOI: 10.1039/C39860000954

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