5-Amino-1-β-D-ribofuranosylimidazole-4-carboxamide (‘AICA-riboside’, 2) has been converted into [15N] guanosine [label either at N-1 (1b) or NH2(1c)]; the mechanism of formation the pyrimidine ring in the nucleoside has been elucidated.
B. T. Golding, P. K. Slaich and W. P. Watson, J. Chem. Soc., Chem. Commun., 1986, 901 DOI: 10.1039/C39860000901
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