A number of β-hydroxy-ketones were reduced to anti-1,3-diols with diastereoisomeric excesses exceeding 95%, by a method involving presumed intramolecular transfer of hydrogen from a silicon atom to the carbonyl carbon.
S. Anwar and A. P. Davis, J. Chem. Soc., Chem. Commun., 1986, 831 DOI: 10.1039/C39860000831
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