SCHEDULED MAINTENANCE
The reactions of triphenylphosphine and triphenylarsine with the bicyclic thiazyl heterocycle PhCN5S3 produce the corresponding 3-imino-7-phenyl-1,3,5,2,4,6,8-trithiatetrazocines PhCN4S3NEPh3(E = P or As); the exo- and endo-isomers of PhCN4S3NAsPh3 have been characterized by X-ray crystallography.
R. T. Boeré, A. W. Cordes, S. L. Craig, J. B. Graham, R. T. Oakley and J. A. J. Privett, J. Chem. Soc., Chem. Commun., 1986, 807 DOI: 10.1039/C39860000807
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