The relative rates of formation of CH3· and CF3· from β-scission reactions of trifluoro-t-butoxy radical (1) have been measured to be about 10 : 1 by thermolysing both trifluoro-t-butyl hypochlorite (4) and bis(trifluoro-t-butyl) peroxydicarbonate (14) in CCl4 at 160 and 140 °C.
X. Jiang, X. Li and K. Wang, J. Chem. Soc., Chem. Commun., 1986, 745 DOI: 10.1039/C39860000745
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