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Issue 9, 1986
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Remarkable rearrangement–dissociation processes of gaseous protonated methyl formate involving ion–dipole complexes

Abstract

Collision induced decarbonylation of 13C, 18O-labelled protonated methyl formate, HC(OH)O*C*H3, involves the loss of both CO (40%) and CO*; the intermediacy of proton-bound dimers and ion–dipole complexes is invoked to explain the mechanisms.

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Article information


J. Chem. Soc., Chem. Commun., 1986, 728-730
Article type
Paper

Remarkable rearrangement–dissociation processes of gaseous protonated methyl formate involving ion–dipole complexes

B. van Baar, H. Halim, J. K. Terlouw and H. Schwarz, J. Chem. Soc., Chem. Commun., 1986, 728
DOI: 10.1039/C39860000728

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