SCHEDULED MAINTENANCE
Collision induced decarbonylation of 13C, 18O-labelled protonated methyl formate, HC(OH)O*C*H3, involves the loss of both CO (40%) and CO*; the intermediacy of proton-bound dimers and ion–dipole complexes is invoked to explain the mechanisms.
B. van Baar, H. Halim, J. K. Terlouw and H. Schwarz, J. Chem. Soc., Chem. Commun., 1986, 728 DOI: 10.1039/C39860000728
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