Issue 9, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Carbonylation of (ButO)3W[triple bond, length half m-dash]CNMe2 and (PriO)3(py)2W[triple bond, length half m-dash]CNMe2(py = pyridine): two different modes of carbon–carbon bond formation

Malcolm H. Chisholm,   John C. Huffman  and  Nancy S. Marchant  

Abstract

Addition of CO (1 atm) to hydrocarbon solutions of (ButO)3W[triple bond, length half m-dash]CNMe2, (1), leads to [(ButO)3W(µ-OCCNMe2)]2, (3), by coupling of the carbonyl and alkylidyne carbon atoms whereas, under similar conditions, (PriO)3(py)2W[triple bond, length half m-dash]CNMe2, (2), and CO give (CO)2(PriO)W(µ-OPri)3W(OPri)2[η2-C2(NMe2)2], (4), via alkylidyne–alkylidyne carbon coupling.

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Article information

DOI
https://doi.org/10.1039/C39860000717
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 717-718

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Carbonylation of (ButO)3W[triple bond, length half m-dash]CNMe2 and (PriO)3(py)2W[triple bond, length half m-dash]CNMe2(py = pyridine): two different modes of carbon–carbon bond formation

M. H. Chisholm, J. C. Huffman and N. S. Marchant, J. Chem. Soc., Chem. Commun., 1986, 717 DOI: 10.1039/C39860000717

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