Observation of an indirect, negative 1H →1H →13C nuclear Overhauser effect (n.O.e.) may be an alternative method for oligosaccharide sequencing where the interglycosidic 1H{1H} n.O.e. can be efficiently ‘relayed’ to the directly bonded anomeric carbon or the glycosylated carbon nucleus.
K. E. Kövér and G. Batta, J. Chem. Soc., Chem. Commun., 1986, 647 DOI: 10.1039/C39860000647
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