Homo- and hetero-dinuclear, diamagnetic and paramagnetic complexes of general formula {[MeC(CH2PPh2)3]Rh(µ-H)3M(L)}n+[M = Rh, Co, Ni, L = MeC(CH2PPh2)3; M = Fe, L = MeC(CH2PEt2)3] have been synthesized and characterized; the electrochemical behaviour of the compounds shows that they reversibly undergo multisequential one-electron redox changes.
C. Bianchini, A. Meli and P. Zanello, J. Chem. Soc., Chem. Commun., 1986, 628 DOI: 10.1039/C39860000628
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