The synthesis and structural characterization of [Et4N]3[Fe6S6(p-MeC6H4O)6{W(CO)3}2]. A hetero-polynuclear aggregate that contains the [W2Fe6S6]3+ core
Abstract
The synthesis and structural (crystallographic and spectroscopic) characterization of the new heteropolymetallic [Et4N]3[Fe6S6(p-MeC6H4O)6{W(CO)3}2] cluster is described; the anion core consists of a W2Fe6 cube with the two W atoms located in opposite corners on the elongated body diagonal.