The direction of the carbonyl-orientation in a solid amide-rotamer of 3-[N-methyl-N-(R)-α-methylbenzyl]carbamoly-1,2,4-trimethylpyridinium iodide is governed by the (R)-chirality in the amide side chain; structures, as determined by X-ray analysis and c.d. spectra, are correlated.
L. A. M. Bastiaansen, J. A. Kanters, F. H. van der Steen, J. A. C. de Graaf and H. M. Buck, J. Chem. Soc., Chem. Commun., 1986, 536 DOI: 10.1039/C39860000536
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