Issue 6, 1986

Convenient synthesis of spiro compounds by the insertion of alkynes into the Pd–C bond of cyclopalladated 2-benzylpyridine

Abstract

Insertion of one alkyne molecule into the Pd–C bond of ortho-palladated 2-benzylpyridine affords an eight-membered organometallic ring; the further insertion of a second alkyne leads to the quantitative formation of an unexpected spiro-compound which has been characterized by an X-ray diffraction study.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 488-490

Convenient synthesis of spiro compounds by the insertion of alkynes into the Pd–C bond of cyclopalladated 2-benzylpyridine

F. Maassarani, M. Pfeffer and G. Le Borgne, J. Chem. Soc., Chem. Commun., 1986, 488 DOI: 10.1039/C39860000488

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