Issue 6, 1986

Palladium-catalysed asymmetric allylations by a chiral allyl ester; the palladium catalysis of (S)-proline allyl ester enamines

Abstract

The palladium-catalysed allylation of the chiral enamines (1ad) followed by acidic hydrolysis, produced optically active 2-allylcyclohexanone (2); the catalysis of the chiral enamine (1a), derived from (S)-proline allyl ester, with tetrakis(triphenyl phosphine)palladium and subsequent acidic hydrolysis led to an almost 100% optical yield of (S)-(–)-(2).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 469-470

Palladium-catalysed asymmetric allylations by a chiral allyl ester; the palladium catalysis of (S)-proline allyl ester enamines

K. Hiroi, K. Suya and S. Sato, J. Chem. Soc., Chem. Commun., 1986, 469 DOI: 10.1039/C39860000469

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements