A diazoalkane complex of titanium
Abstract
(cp)2Ti(PMe3)2(cp =η5-C5H5) and (cp)2Ti(CO)(PMe3) react with diphenyldiazomethane to yield (cp)2Ti(NNCPh2)(PMe3), the crystal structure of which has been determined, containing a monodentate diazoalkane ligand end-on co-ordinated through nitrogen.