The complexation of CH2Cl2 and CH2Br2 by cryptophane-D (2), a new bis-cyclotribenzyl cavitand, has been studied by 1H n.m.r. spectroscopy and the structure of the internal 1 : 1 (2)·CH2Cl2 complex (cavitate) has been determined by single crystal X-ray crystallography.
J. Canceill, M. Cesario, A. Collet, J. Guilhem, C. Riche and C. Pascard, J. Chem. Soc., Chem. Commun., 1986, 339 DOI: 10.1039/C39860000339
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