The compounds cpFe(CO)2H and HMn(CO)5(cp = cyclopentadienyl) react with 1,3-dienes to give the 2-enylmetal products of 1,4-addition of the metal hydrides to the dienes; ClDNP studies indicate that the process involves a radical pair mechanism.
M. J. Thomas, T. A. Shackleton, S. C. Wright, D. J. Gillis, J. P. Colpa and M. C. Baird, J. Chem. Soc., Chem. Commun., 1986, 312 DOI: 10.1039/C39860000312
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