Upon irradiation, tetracyanoethylene (TCNE) in acetonitrile gave 2-amino-1,1-dicyanopropene, while tetracyanoquinodimethane (TCNQ) in isobutyronitrile gave 1-(4-dicyanomethylphenyl)-2-methylpropane-1,1,2-tricarbonitrile; mechanisms involving electron transfer in which liphatic nitriles behave as electron donors are proposed.
K. Tsujimoto, T. Fujimori and M. Ohashi, J. Chem. Soc., Chem. Commun., 1986, 304 DOI: 10.1039/C39860000304
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