Issue 3, 1986

Reaction of 1-arylpropenyl-lithium with t-alkyl bromides. The influence of substituent electronic effects and additives on the course of the reaction

Abstract

The reaction of 1-arylpropenyl-lithium (1a–c) with t-alkyl bromides proceeds by either a nucleophilic substitution or single electron transfer mechanism, the preferred pathway being a function of electronic substituent effects and the absence or presence of tetramethylethylenediamine or hexamethylphosphoramide.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 242-244

Reaction of 1-arylpropenyl-lithium with t-alkyl bromides. The influence of substituent electronic effects and additives on the course of the reaction

J. Tanaka, M. Nojima and S. Kusabayashi, J. Chem. Soc., Chem. Commun., 1986, 242 DOI: 10.1039/C39860000242

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