By using a regiospecifically dideuteriated form of the substrate it is shown that the enzymic conversion of (S)-adenosylmethionine (SAM) into 1-aminocyclopropanecarboxylic acid (ACC) involves an inversion at the α-carbon centre, a feature rarely observed for other pyridoxal phosphate-dependent reactions.
R. Wiesendanger, B. Martinoni, T. Boller and D. Arigoni, J. Chem. Soc., Chem. Commun., 1986, 238 DOI: 10.1039/C39860000238
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