Issue 3, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Kinetic determination of the bond dissociation energy D(Me3SiCMe2CH2–H) and the magnitude of the stabilisation energy in a β-silicon-substituted alkyl radical

Norbert Auner,   Robin Walsh  and  Julian Westrup  

Abstract

A kinetic study of the gas-phase reaction between iodine and Me3SiCMe3 is interpreted to provide a β-silicon stabilisation energy of ca. 12 kJ mol–1 in the Me3SiCMe2CH2· radical.

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Article information

DOI
https://doi.org/10.1039/C39860000207
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 207-208

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Kinetic determination of the bond dissociation energy D(Me3SiCMe2CH2–H) and the magnitude of the stabilisation energy in a β-silicon-substituted alkyl radical

N. Auner, R. Walsh and J. Westrup, J. Chem. Soc., Chem. Commun., 1986, 207 DOI: 10.1039/C39860000207

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