Some 5-methoxy-2-aryl-1,3,4-oxadiazoles undergo a 1,3 O-to-N thermal rearrangement of the methyl group, which takes place unusually easily, and much faster in the solid state than in the melt.
M. Dessolin and M. Golfier, J. Chem. Soc., Chem. Commun., 1986, 38 DOI: 10.1039/C39860000038
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