Issue 12, 1985

The reaction of dibenzylmercury with arenes and cyclohexene on molecular sieves

Abstract

The thermal decomposition of dibenzylmercury in aromatic solvents in the pores of 13X molecular sieve gives benzylated aromatic substitution products, rather than the hydrogen-abstraction and radical combination products obtained in the absence of the zeolite. The intermediacy of an electrophilic benzyl ‘cation’ is postulated.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1985, 2041-2043

The reaction of dibenzylmercury with arenes and cyclohexene on molecular sieves

H. Aǧirbas and R. A. Jackson, J. Chem. Soc., Perkin Trans. 2, 1985, 2041 DOI: 10.1039/P29850002041

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