Issue 10, 1985
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Absence of rearrangement in reactions of the compounds (Me3Si)3CSiMe(OMe)I, (Me3Si)3CSiMe(OH)I, and (Me3Si)3CSi(OMe)2I with electrophilic reagents

Cohn Eaborn  and  David E. Reed  

Abstract

The compounds TsiSiMe(OMe)I and TsiSi(OMe)2I [Tsi =(Me3Si)3C] have been prepared and found, unexpectedly, to give only unrearranged products of the type TsiSiMe(OMe)Z and TsiSi(OMe)2Z (Z = Cl or Y) on treatment with ICl or with silver salts AgY. The hydroxy-iodide TsiSiMe(OH)I likewise gives only TsiSiMe(OH)CI on treatment with ICl.

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Article information

DOI
https://doi.org/10.1039/P29850001695
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1985, 1695-1697

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Absence of rearrangement in reactions of the compounds (Me3Si)3CSiMe(OMe)I, (Me3Si)3CSiMe(OH)I, and (Me3Si)3CSi(OMe)2I with electrophilic reagents

C. Eaborn and D. E. Reed, J. Chem. Soc., Perkin Trans. 2, 1985, 1695 DOI: 10.1039/P29850001695

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