Kinetic studies confirm that the silver(I) ion-promoted reaction of disulphides with sulphinate ions proceeds via formation of a disulphide–Ag+ complex. Nucleophilic attack by sulphinate sulphur at the sulphenyl centre of the complex leads to silver alkyl sulphide and thiosulphonate. Under favourable conditions the 1 : 1 disulphide–silver complex can be isolated.
J. S. Sandhu and J. G. Tillett, J. Chem. Soc., Perkin Trans. 2, 1985, 879 DOI: 10.1039/P29850000879
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