The chlorine-35 and antimony-121 and -123 nuclear quadrupole resonance spectra of five-membered ring chelate derivatives of antimony pentachloride
Abstract
The 35Cl and 121,123Sb quadrupole resonance spectra of several five-membered ring chelate derivatives of antimony pentachloride are reported. Four of these are of known structure: the singly chelated derivatives of tropolone, N-methyloxamide, and NN′-dimethyloxadiamide, and the doubly chelated derivative of oxalic acid. The doubly chelated derivative of NN′-dimethyloxadiamide, of unknown crystal structure, has also been measured. The 35Cl resonance frequencies of the axial and equatorial chlorine atoms are quite distinct and, for the tropolone complex, imply a 10% difference between the ionicity of the axial and equatorial groups, and are affected to a different extent by the nature of the chelate group. The large value of the 121Sb asymmetry parameter of the oxalate complex is satisfactorily explained by the observed small angular deformations of the geometry from that of a regular octahedron.