Issue 2, 1985

Effects of an inhomogeneous concentration distribution on rate constants of radical reactions in liquids obtained by time-resolved and modulation spectroscopy

Abstract

Non-uniform concentration distributions caused by photochemical generation of radicals in solution affect kinetic responses observed in experiments using time-resolved or modulated detection. Formulas for the correct analysis of kinetic measurements are derived for various experimental conditions. It is shown that the effects are generally much smaller than stated previously by other authors, and this is verified by the results of experiments on self-termination reactions of t-butyl and benzyl radicals.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1985, 213-220

Effects of an inhomogeneous concentration distribution on rate constants of radical reactions in liquids obtained by time-resolved and modulation spectroscopy

H. Fischer, H. Paul, K. Münger and T. Dschen, J. Chem. Soc., Perkin Trans. 2, 1985, 213 DOI: 10.1039/P29850000213

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