Rate constfnts for hydrogen or deuterium abstraction from bis-(2,4-dinitrophenyl)methane by methoxide ion have been determined in methanol, methanol–dimethyl sulphoxide, and deuteriated methanol solutions, together with the temperature variation of proton abstraction and carbanion protonation for the hydrogen-containing substrate in methanol. Isotope and solvent effects confirm the rate-limiting proton transfer.
P. G. Farrell, P. Fogel, A. Chatrousse, J. Lelièvre and F. Terrier, J. Chem. Soc., Perkin Trans. 2, 1985, 51 DOI: 10.1039/P29850000051
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