A two-step synthesis of pyromellitimide-bridged porphyrins is described. These compounds offer a convenient route to model photosynthetic systems of predetermined geometry. Very strong quenching of the fluorescence emission bands on irradiation at the Soret wavelength is suggestive of electron transfer interactions.
J. A. Cowan and J. K. M. Sanders, J. Chem. Soc., Perkin Trans. 1, 1985, 2435 DOI: 10.1039/P19850002435
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