Treatment of the erythro-β-hydroxyalkyldibenzophosphole oxide (6), derived from (E)-stilbene oxide and lithiodibenzophosphole, with 1,5-diazabicyclo[5.4.0]undec-5-ene (DBU) in dimethyl sulphoxide (DMSO) affords (Z)-stilbene with high stereospecificity.
T. G. Roberts and G. H. Whitham, J. Chem. Soc., Perkin Trans. 1, 1985, 1953 DOI: 10.1039/P19850001953
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