The structure elucidation of a novel trichothecene glycoside, 15-acetoxy-3α-hydroxy-4β-(α-D-glucopyranosyloxy)-12,13-epoxytrichothec-9-ene, is based on a detailed study of its one- and two-dimensional 1H and 13C n.m.r. spectra, and chemical reactions. The metabolite displays a reduced toxicity when compared with other trichothecene metabolites in several biological systems.
C. P. Gorst-Allman, P. S. Steyn, R. Vleggaar and C. J. Rabie, J. Chem. Soc., Perkin Trans. 1, 1985, 1553 DOI: 10.1039/P19850001553
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