Issue 0, 1985

Secondary mould metabolites. Part 13. Fungal perylenequinones: phleichrome, isophleichrome, and their endoperoxides

Abstract

The helix-shaped, fungal pigment phleichrome has been isomerized to isophleichrome. The axial chirality and absolute configuration of the side-chain carbons of both perylenequinones have been established. Photo-oxidation of both compounds occurs stereospecifically to give their endoperoxides, whose structure and stereochemistry results from a detailed analysis of their n.m.r. spectra.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1985, 1387-1392

Secondary mould metabolites. Part 13. Fungal perylenequinones: phleichrome, isophleichrome, and their endoperoxides

A. Arnone, L. Camarda, G. Nasini and L. Merlini, J. Chem. Soc., Perkin Trans. 1, 1985, 1387 DOI: 10.1039/P19850001387

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